From: hackbard Date: Fri, 30 Apr 2004 08:30:34 +0000 (+0000) Subject: emrs 2004 pre 1 X-Git-Url: https://hackdaworld.org/gitweb/?a=commitdiff_plain;h=3de690b776e1a9836f6490a0e8541c45f852579b;p=lectures%2Flatex.git emrs 2004 pre 1 --- diff --git a/nlsop/nlsop_emrs_2004.tex b/nlsop/nlsop_emrs_2004.tex index a35059e..31bbb7f 100644 --- a/nlsop/nlsop_emrs_2004.tex +++ b/nlsop/nlsop_emrs_2004.tex @@ -75,18 +75,20 @@ A model describing the formation of nanometric, selforganized, regularly arrange As a result of supersaturation of carbon atoms in silicon at high concentrations there is a nucleation of spherical $SiC_x$ precipitates. Carbon implantations at much higher implantation temperatures usually lead to the precipitation of cubic $SiC$ ($3C-SiC$, $a=0.436 \, nm$). The lattice misfit of almost $20\%$ of $3C-SiC$ causes a large interfacial energy with the crystalline $Si$ matrix \cite{6}. This energy could be reduced if one of the phases exists in the amorphous state. Energy filtered XTEM studies in \cite{4} have revealed that the amorphous phase is more carbon-rich than the crystalline surrounding. In addition, annealing experiments have shown that the amorphous phase is stable against crystallization at temperatures far above the recrystallization temperatures of amorphous $Si$. Prolonged annealing at $900 \, ^{\circ} \mathrm{C}$ turns the lamellae into ordered chains of amrphous and crystalline ($3C-SiC$) nanoprecipitates \cite{7} demonstrating again the carbon-rich nature of amorphous inclusions. Since at the implantation conditions chosen, pure $a-Si$ would recrystallize by ion beam induced crystallization \cite{8}, it is understandable that it is the carbon-rich side of the two phases which occurs in the amorphous state in the present phase separation process. -Stoichiometric $SiC$ has a smaller atomic density than $c-Si$. A reduced density is also assumed for substoichiometric $a-SiC_x$. Hence the amorphous $SiC_x$ tends to expand and as a result compressive stress is applied on the $Si$ host lattice. As the process occurs near the target surface, stress is relaxing in vertical direction and there is mainly lateral stress remaining. Thus volumes between amorphous inclusions will more likely turn into an amorphous phase as the stress hampers the rearrangement of atoms on regular lattice sites. In contrast $a-Si$ volumes located in a crystalline neighbourhood will recrystallize in all probability. Carbon is assumed to diffuse from the crystalline to the amorphous volumes in order to reduce the supersaturation of carbon in the crystalline interstices. As a consequence the amorphous volumes accumulate carbon. +Stoichiometric $SiC$ has a smaller atomic density than $c-Si$. A reduced density is also assumed for substoichiometric $a-SiC_x$. Hence the amorphous $SiC_x$ tends to expand and as a result compressive stress is applied on the $Si$ host lattice. As the process occurs near the target surface, stress is relaxing in vertical direction and there is mainly lateral stress remaining. Thus volumes between amorphous inclusions will more likely turn into an amorphous phase as the stress hampers the rearrangement of atoms on regular lattice sites. In contrast $a-Si$ volumes located in a crystalline neighbourhood will recrystallize in all probability. + +Carbon is assumed to diffuse from the crystalline to the amorphous volumes in order to reduce the supersaturation of carbon in the crystalline interstices. As a consequence the amorphous volumes accumulate carbon. \newpage \section{Simulation} Before discussing the implementation some assumptions and approximations have to be made. Figure \ref{trim} shows the stopping powers and carbon concentration profile calculated by TRIM \cite{9}. The depth region we are interested in is between $0-300 \, nm$ (furtheron called simulation window), the region between the target surface and the beginning of the continuous amorphous $SiC_x$ layer at the implantation conditions of Figure \ref{xtem}. The nuclear stopping power and the implantation profile can be approximated by a linear function of depth within the simulation window. -The target is devided into $64 \times 64 \times 100$ cells with a side length of $3 \, nm$. Ech of it has a state (crystalline/amorphous) and keeps the local carbon concentration. The cell is addressed by a position vector $\vec r = (k,l,m)$, where $k$, $l$, $m$ are integers. +The target is devided into $64 \times 64 \times 100$ cells with a side length of $3 \, nm$. Each of it has a state (crystalline/amorphous) and keeps the local carbon concentration. The cell is addressed by a position vector $\vec r = (k,l,m)$, where $k$, $l$, $m$ are integers. -The probability of amorphization is assumed to be proportional to the nuclear stopping power. A local probability of amorphization at any point in the target is composed of three contributions, the ballistic amorphization, a carbon-induced and a stress-induced amorphization. The ballistic amorphization is proportional to the nuclear stopping power as mentioned before. The carbon-induced amorphization is a linear function of the local carbon concentration. The stress-induced amorphization is proportional to the compressive stress originating from the amorphous volumes in the vicinity, the stress amplitude decreasing with the square of distance $d=|\vec r - \vec r'|$. Thus the probability of a crystalline volume getting amorphous can be calculated as +The probability of amorphization is assumed to be proportional to the nuclear stopping power. A local probability of amorphization at any point in the target is composed of three contributions, the ballistic amorphization, a carbon-induced and a stress-induced amorphization. The ballistic amorphization is proportional to the nuclear stopping power as mentioned before. The carbon-induced amorphization is a linear function of the local carbon concentration. The stress-induced amorphization is proportional to the compressive stress originating from the amorphous volumes in the vicinity, the stress amplitude decreasing with the square of distance $d=|\vec r - \vec{r'}|$. Thus the probability of a crystalline volume getting amorphous can be calculated as \[ - p_{c \rightarrow a}(\vec r) = p_{b} + p_{c} \, c_{carbon}(\vec r) + \sum_{amorphous \, neighbours} \frac{p_{s} \, c_{carbon}(\vec r)}{d^2} + p_{c \rightarrow a}(\vec r) = p_{b} + p_{c} \, c_{carbon}(\vec r) + \sum_{amorphous \, neighbours} \frac{p_{s} \, c_{carbon}(\vec{r'})}{d^2} \] with $p_{b}$, $p_{c}$ and $p_{s}$ being simulation parameters to weight the three different mechanisms of amorphization. The probability $p_{a \rightarrow c}$ of an amorphous volume to turn crystalline should behave contrary to $p_{c \rightarrow a}$ and is thus assumed as $p_{a \rightarrow c} = 1 - p_{c \rightarrow a}$. @@ -105,20 +107,20 @@ Figure \ref{c-xtem} shows a comparison of a simulation result and a XTEM bright- Simulations with different model parameters allow to specify conditions for observing lamellar structures. -First runs with a simplified version of the program have shown that it is essential to assume low amorphization probabilities to avoid to early complete amorphization of the whole cell ensemble. Instead small amorphization parameters $p_b$, $p_c$, $p_s$ and a large number of simulation steps are required to observe lamellar structures. This finding is an agreement to the fact that of the bais of the low nuclear energy deposition of the light carbon ions in silicon, amorphization would not be expected at all at this elevated target temperatures \cite{4} and thus carbon mediated amorphization has to be taken into account to explain the amorphization process. +First runs with a simplified version of the program have shown that it is essential to assume low amorphization probabilities to avoid to early complete amorphization of the whole cell ensemble. Instead small amorphization parameters $p_b$, $p_c$, $p_s$ and a large number of simulation steps are required to observe lamellar structures. This finding is an agreement to the fact that of the basis of the low nuclear energy deposition of the light carbon ions in silicon, amorphization would not be expected at all at this elevated target temperatures \cite{4} and thus carbon mediated amorphization has to be taken into account to explain the amorphization process. -Figure \ref{zdiff} shows the results of two identical simulation runs with diffusion in $z$-direction switched off and on. The lamellar structures appear only if diffusion in $z$-direction is enabled. Amorphous volumes denude the neighbouring crystalline layers of carbon. In consequence the stability of such cells against recrystallization is enhanced, the probability to amorphizise crystalline cells in the same depth is increased and the amorphization in the carbon denuded cells and their lateral vicinity is decreased. This fortifies the formation of lamellar precipitates. The result hilights the importance of the selforganization process. +Figure \ref{zdiff} shows the results of two identical simulation runs with diffusion in $z$-direction switched off and on. The lamellar structures appear only if diffusion in $z$-direction is enabled. Amorphous volumes denude the neighbouring crystalline layers of carbon. In consequence the stability of such cells against recrystallization is enhanced, the probability to amorphizise crystalline cells in the same depth is increased and the amorphization in the carbon denuded cells and their lateral vicinity is decreased. This fortifies the formation of lamellar precipitates. The result hilights the importance of the diffusion in $z$-direction for the selforganization process. In Figure \ref{diffrate} two simulation results with different diffusion rates are compared. Higher diffusion rates cause a larger depth domain of lamellar structure. This can be understood since higher diffusion rates result in amorphous volumes holding more carbon which consequently stabilizes the amorphous state. In case of slower diffusion rates (Figure 6b) the redistribution of carbon is too slow to allow for an effective agglomeration of carbon atoms in amorphous cells to stabilize the amorphous state against recrystallization. This results in a smaller total amount of amorphous material in Figure 6b compared to Figure 6a. The stabilization occurs only at a depth larger than $240 \, nm$ where the total concentration of carbon is high enough. The sufficient stabilization of amorphous volumes in this deeper depth zone enables also the more effective contribution of the stress mediated amorphization. -Figure \ref{compl-str} shows the extension of amorphous lamellae in plain view for two consecutive slices $m$ and $m+1$ of the ensemble. It is obvious that amorphous and crystalline lamellae have a complementary arrangement in neighbouring slices (Figure 7a,b) which again is a result of the carbon accumulation in the amorphous lamellae. This can be clearly seen by comparison of the corresponding carbon maps in Figure 7c,d. +The influence of the stress term $p_s$ is considered in Figure \ref{stress}. For otherwise the same conditions as in Figure 6b calculations with decreased $p_s$ in Figure 7b,c,d show a systematically reduced extension of the lamellae zone. The mean diameter of amorphous lamellae decreases with decreasing $p_s$. Both observations support the assumption of stress mediated amorphization as a mechanism contributing to lamellar formation. -%Finally fourier transformation was applied on experimental XTEM measurements and simulatin results. \ldots +Figure \ref{compl-str} shows the extension of amorphous lamellae in plain view for two consecutive slices $m$ and $m+1$ of the ensemble. It is obvious that amorphous and crystalline lamellae have a complementary arrangement in neighbouring slices (Figure 8a,b) which again is a result of the carbon accumulation in the amorphous lamellae. This can be clearly seen by comparison of the corresponding carbon maps in Figure 8c,d. \newpage \section{Summary and conclusion} -A simple model explaining the selforganization process of lamellar, amorphous precipitates was introduced. In addition the implementation of that model to reasonable simulation code was discussed. This simulation code is able to reproduce experimental results. Furthermore the formation of these lamellar structures get traceable by the simulation code. Necessary conditions, i.e. diffusion in $z$-direction can be stated. We found the diffusion rate to influence the depth distribution of lamellar precipitates. Not easily measurable information is gained by the simulation like the complementary configuration of amorphous and crystalline arrays in successive layers. +A simple model explaining the selforganization process of lamellar, amorphous precipitates during high dose ion implantation is introduced. The implementation of the model in a simulation code is described. The simulation is able to reproduce the experimentally observed formation of lamellae. The evolution of these lamellar structures gets traceable by the simulation. The weight of different mechanisms which contribute to the selforganization process is explored by variation of simulation parameters. It is found that diffusion in $z$-direction and stress mediated amorphization are necessary to create ordered arrays of amorphous, lamellar precipitates. Thus by simulation, information is gained about the selforganization process which is not easily accessible by experimental techniques. \newpage @@ -144,48 +146,55 @@ A simple model explaining the selforganization process of lamellar, amorphous pr \begin{figure}[!h] \begin{center} \includegraphics[width=17cm]{k393abild1_e.eps} -\caption[Cross-sectional TEM image of $180 \, keV C^+$ in $Si$ with a dose of $4.3 \times 10^{17} \, cm^{-2}$ and substrate temperature of $150 \,^{\circ} \mathrm{C}$. and substrate temperature of $150 \,^{\circ} \mathrm{C}$ Lamellar and spharical amorphous inclusions are marked by $L$ and $S$.]{} \label{xtem} +\caption[XTEM image of a $Si$ sample implanted with $180 \, keV \, C^+$ ions at a dose of $4.3 \times 10^{17} \, cm^{-2}$ and a substrate temperature of $150 \,^{\circ} \mathrm{C}$, lamellar and spherical amorphous inclusions are marked by $L$ and $S$.]{} \label{xtem} \end{center} \end{figure} \begin{figure}[!h] \begin{center} \includegraphics[width=17cm]{model1_e.eps} -\caption[Rough model explaining the selforganization of amorphous $SiC_x$ precipitates and the evolution into ordered lamellae with increasing dose.]{} \label{model} +\caption[Model explaining the selforganization of amorphous $SiC_x$ precipitates and the evolution into ordered lamellae with increasing dose.]{} \label{model} \end{center} \end{figure} \begin{figure}[!h] \begin{center} \includegraphics[width=14cm]{2pTRIM180C.eps} -\caption[Stopping powers and concentration profile calculated by TRIM.]{} \label{trim} +\caption[Nuclear and electronic stopping powers and concentration profile of a simulation of $180 \, keV \, C^+$ ions implanted in $Si$ calculated by TRIM.]{} \label{trim} \end{center} \end{figure} \begin{figure}[!h] \begin{center} \includegraphics[width=15cm]{if_cmp2_e.eps} -\caption[Comparison of a simulation result and a cross-sectional TEM snapshot of $180 \, keV$ implanted carbon in silicon at $150 \,^{\circ} \mathrm{C}$ with $4.3 \times 10^{17} cm^{-2}$.]{} \label{c-xtem} +\caption[Comparison of a simulation result and a XTEM image of $180 \, keV$ implanted carbon into silicon at $150 \,^{\circ} \mathrm{C}$ at a dose of $4.3 \times 10^{17} cm^{-2}$.]{} \label{c-xtem} \end{center} \end{figure} \begin{figure}[!h] \begin{center} -\includegraphics[width=8cm]{mit_ohne_diff_e.eps} +\includegraphics[width=8cm]{mit_ohne_diff_big_e.eps} \caption[Two identical simulation runs with diffusion switched off (left) and on (right)]{} \label{zdiff} \end{center} \end{figure} \begin{figure}[!h] \begin{center} -\includegraphics[width=8cm]{high_low_ac-diff_e.eps} +\includegraphics[width=8cm]{high_low_ac-diff_big_e.eps} \caption[Two identical simulation runs with different diffusion rates $d_r$]{} \label{diffrate} \end{center} \end{figure} \begin{figure}[!h] \begin{center} -\includegraphics[width=10cm]{all_z-z_plus_1.eps} +\includegraphics[width=8cm]{high_to_low_a_e.eps} +\caption[Four identical simulation runs with different simulation parameter $p_s$]{} \label{stress} +\end{center} +\end{figure} + +\begin{figure}[!h] +\begin{center} +\includegraphics[width=10cm]{all_z-z_plus_1_big.eps} \caption[Amorphous/crystalline (a,b) and carbon distribution (c,d) view of two consecutive slices $m$ and $m+1$]{} \label{compl-str} \end{center} \end{figure}